The third practice session for the 2014 Spanish Grand Prix would see Williams Martini drivers Felipe Massa and Valtteri Bottas finish in fourth and eleventh.

Pos  Driver         	Team		      Time      Laps
 1. Nico Rosberg       Mercedes              1m25.887s  16
 2. Lewis Hamilton     Mercedes              1m26.756s  9 
 3. Fernando Alonso    Ferrari               1m27.188s  15
 4. Felipe Massa       Williams-Mercedes     1m27.223s  10
 5. Romain Grosjean    Lotus-Renault         1m27.682s  18
 6. Kevin Magnussen    McLaren-Mercedes      1m27.806s  16
 7. Daniel Ricciardo   Red Bull-Renault      1m27.808s  12
 8. Jenson Button      McLaren-Mercedes      1m28.006s  11
 9. Pastor Maldonado   Lotus-Renault         1m28.076s  19
10. Sebastian Vettel   Red Bull-Renault      1m28.085s  20
11. Valtteri Bottas    Williams-Mercedes     1m28.101s  12
12. Jean-Eric Vergne   Toro Rosso-Renault    1m28.242s  16
13. Daniil Kvyat       Toro Rosso-Renault    1m28.298s  16
14. Kimi Raikkonen     Ferrari               1m28.419s  16
15. Sergio Perez       Force India-Mercedes  1m28.571s  13
16. Nico Hulkenberg    Force India-Mercedes  1m28.668s  13
17. Adrian Sutil       Sauber-Ferrari        1m28.715s  16
18. Esteban Gutierrez  Sauber-Ferrari        1m28.865s  18
19. Max Chilton        Marussia-Ferrari      1m30.169s  15
20. Jules Bianchi      Marussia-Ferrari      1m30.670s  12
21. Kamui Kobayashi    Caterham-Renault      1m30.712s  18
22. Marcus Ericsson    Caterham-Renault      1m31.559s  19